(E)-4-Methoxy-N′-(4-methylbenzylidene)benzohydrazide

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Synthesis and crystal structure of Schiff-base compound (E)-4-methoxy-N- (4-hydroxybenzylidene) aniline

New Schiff-base compound (E)-4-methoxy-N-(4-hydroxybenzylidene) aniline has been synthesized from the reaction of 4-hydroxybenzaldehyde with 4-methoxyaniline in methanol at 50ºC, and has been characterized by using elemental analysis and FT-IR spectroscopy. The crystal structure of the title compound has been determined by single crystal X-ray diffraction study. The title compound crystallizes ...

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(E)-N′-(4-Eth­oxy­benzyl­idene)-4-hy­droxy­benzohydrazide dihydrate

The benzohydrazide mol-ecule of the title compound, C(16)H(16)N(2)O(3)·2H(2)O, exists in a trans conformation with respect to the C=N double bond. The central O=C-NH-N=C plane [r.m.s. deviation of 0.0165 (1) Å for the five non-H atoms] makes dihedral angles of 6.04 (8) and 2.38 (8)°, respectively, with the hy-droxy- and eth-oxy-substituted benzene rings. The dihedral angle between these benzene...

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(E)-4-Chloro-N′-(4-hydroxy­benzyl­idene)­benzohydrazide

The mol-ecule of the title compound, C(14)H(11)ClN(2)O(2), displays a trans configuration with respect to the C=N double bond. The dihedral angle between the two benzene rings is 12.8 (3)°. In the crystal structure, mol-ecules are linked through inter-molecular O-H⋯O and N-H⋯O hydrogen bonds and C-H⋯π inter-actions, forming a three-dimensional network.

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(E)-4-Hydr­oxy-N′-(4-nitro­benzyl­idene)benzohydrazide

The mol-ecule of the title compound, C(14)H(11)N(3)O(4), is approximately planar, the dihedral angle between the planes of the two substituted benzene rings being 2.54 (7)°. The mol-ecule exists in a trans configuration with respect to the central methyl-idene unit. In the crystal structure, mol-ecules are linked through inter-molecular O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming layers para...

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3-Methoxy-4-(4-nitro­benz­yloxy)­benzaldehyde

In the title compound, C(15)H(13)NO(5), the vanillin group makes a dihedral angle of 4.95 (8)° with the benzene ring of the nitro-benzene group. The packing is stabilized by weak, non-classical inter-molecular C-H⋯O inter-actions which link mol-ecules into chains running along the c axis.

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ژورنال

عنوان ژورنال: IUCrData

سال: 2016

ISSN: 2414-3146

DOI: 10.1107/s2414314616004314